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Unusual spin-transition anomaly in the crossover system [Fe(2-pic)3]Cl2·EtOH

✍ Scribed by H. Köppen; E.W. Müller; C.P. Köhler; H. Spiering; E. Meissner; P. Gütlich


Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
349 KB
Volume
91
Category
Article
ISSN
0009-2614

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The structure changes and the spin phase
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Tne wsta! structure of the spin crossover complex [re(l-pic)l] CIZ -EtOH in its high spin stare (798. 150 K) and ION skin smtc (90 6) has been determined. The cry~ak are monoclinic. PZl/c \xith Z=4 in. the two spin states. Pronounced clung= in tire Fe-X bond distance (Z-I% A for high spin. 2.013 X f