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Thermodynamics of the spin transition in [FexZn1−x(2-pic)3]Cl2 · EtOH

✍ Scribed by R. Jakobi; H. Spiering; P. Gütlich


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
879 KB
Volume
53
Category
Article
ISSN
0022-3697

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The structure changes and the spin phase
✍ Mami Mikami; Michiko Konno; Yoshihiko Saito 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 367 KB

Tne wsta! structure of the spin crossover complex [re(l-pic)l] CIZ -EtOH in its high spin stare (798. 150 K) and ION skin smtc (90 6) has been determined. The cry~ak are monoclinic. PZl/c \xith Z=4 in. the two spin states. Pronounced clung= in tire Fe-X bond distance (Z-I% A for high spin. 2.013 X f