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The effect of a magnetic field on the high-spin α low-spin transition in [Fe(phen)2(NCS)2]

✍ Scribed by Y. Qi; E.W. Müller; H. Spiering; P. Gütlich

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
216 KB
Volume
101
Category
Article
ISSN
0009-2614

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✦ Synopsis

The transition temperature of [Fe@hen)z(NCS)z ] measured by susceptibility measurements in an applied tield of 1 T shifts by -0.11 f 0.04 K when the field is increased to 55 T. This shift is predicted on the basis of the known magnetic susceptibility and specific heat data.

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Investigation of the low-spin to high-sp
Investigation of the low-spin to high-spin transition in a novel [Fe(pmea)(NCS)2] complex by IR and Raman spectroscopy and DFT calculations
✍ Georg Brehm; Markus Reiher; Boris Le Guennic; Michael Leibold; Siegfried Schindl 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 649 KB

## Abstract The X‐ray structures of the novel spin crossover complex [Fe(pmea)(NCS)~2~] with pmea = (bis[(2‐pyridyl)methyl]‐2‐(2‐pyridyl)ethylamin) were determined in its low‐spin (singlet, LS) and high‐spin state (quintet, HS) and compared with the optimized geometries produced by BP86 calculation