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The influence of reactant vibrational excitation on the O(3P) + O†3 bimolecular reaction rate

✍ Scribed by Gary A. West; Ralph E. Weston Jr.; George W. Flynn

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 456 KB
Volume: 56
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)89008-3

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✦ Synopsis

Atomic resonance fluorescence bas been used to monitor the disappearance rate of oxygen atoms in tbe presence of viirationally eTched ozone produced by a pulsed CO2 laser. An upper limit bas been determined for the rate coefficient of the Oc3P) + OT bimolecular reaction. Comparison with a previpusly measured rate coefficient for deactivation of 0: by 0(3P> indicat2 that at most a small fraction <<30%) of the 03 relaxation is due to the laser enhanced reaction.

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