✦ LIBER ✦

Studies on the influence of vibrational excitation of CF2Cl* radicals on the rate of their reaction with HCl

✍ Scribed by A.B. Vakhtin; V.V. Vizhin; A.K. Petrov

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 324 KB
Volume: 108
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)80374-7

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✦ Synopsis

A method is proposed for studying the influence of vibrational excilation of radicals on their reactivity in bimolecular reactions. Investigations of the reaction CFZCI + HCI 4 CF2 HCI + Cl by this method show for the first time that this rexlion isaccelcrated by vibrational cscitntion of CFzCI* radicals. Under rhc csperimcntal conditions. it WIS round lhar X-;/X-, 2 6.0.

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