✦ LIBER ✦
Control of product channels by addition of vibrational or electronic energy to the reactions of Xe(6s) atoms with CF3Cl, CF2Cl2 and CF2HCl molecules
✍ Scribed by J. Xu; A.R. Slagle; D.W. Setser; J.C. Ferrero
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 799 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
An order of magnitude enhancement of the XeCl(B,C) formation rate constants was observed for the 300 K reactions of Xe( 6p[ l/2] 0 and [ 3/2]*) atoms with CF&l, CF& and CF,HCl, relative to the reactions of Xe( 6s, 3P2) atoms. Similar large XeCl( B,C) formation enhancement factors were found for reactions of the vibrationally excited molecules ( = 2 eV), produced by COz-laser irradiation, with Xe( 6s, 3P2) atoms. These results correlate with the energy dependence of the dissociative electron attachment cross sections of these molecules.