𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Influence of Polar and Steric Effects on the Selectivity of the β-Cleavage of Alkyl Radicals

✍ Scribed by Dr. Kurt Klenke; Priv.-Doz. Dr. Jürgen O. Metzger; Dipl.-Chem. Stefan Lübben

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
336 KB
Volume
27
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polar Effects in the Addition of Alkyl R
Polar Effects in the Addition of Alkyl Radicals to Olefins
✍ Priv.-Doz. Dr. Bernd Giese; Dipl.-Chem. Jürgen Meister 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 198 KB 👁 1 views

**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett ϱ values. Alkyl radicals R^˙^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image

The Effect of Solvent on the Stability o
The Effect of Solvent on the Stability of mero-Substituted Alkyl Radicals
✍ Dr. Hans-Dieter Beckhaus; Prof. Dr. Christoph Rüchardt 📂 Article 📅 1987 🏛 John Wiley and Sons 🌐 English ⚖ 249 KB 👁 2 views

cm -I. 665 I independent reflections (Siemens AED diffractometer, 0 in the range 3-23", W28 scan technique and Nb-filtered radiation. The structure was solved by direct and Fourier methods and refined by fullmatrix least-squares analysis on the basis of 3278 observed reflections [ I r 2 n ( l ) ] wi

Effect of diethylstilbestrol on the poly
Effect of diethylstilbestrol on the polymerization and alkylation of tubulin
✍ Veena Prasad; Stuart E. Garber; Richard F. Ludueña 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 271 KB 👁 2 views

Diethylstilbestrol is a drug used to treat prostate cancer. It is thought to bind to tubulin, the subunit protein of microtubules, at the colchicine-binding site. We examined its interaction with tubulin in more detail. Diethylstilbestrol inhibits microtubule assembly, and seems to do so more effect