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Steric Effects in the Addition of Alkyl Radicals to Alkenes

✍ Scribed by Prof. Dr. Bernd Giese; Dipl.-Chem. Stephen Lachhein

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 134 KB
Volume: 20
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.198109671

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**The presence of a negative partial charge on the benzylic carbon atom in the transition state** __(1)__ can be deduced from the experimentally determinable Hammett ϱ values. Alkyl radicals R^˙^ are accordingly seen to develop nucleophilic properties during addition to olefins. equation image

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