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The Effect of Solvent on the Stability of mero-Substituted Alkyl Radicals

✍ Scribed by Dr. Hans-Dieter Beckhaus; Prof. Dr. Christoph Rüchardt

Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
249 KB
Volume
26
Category
Article
ISSN
0044-8249

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✦ Synopsis

cm -I. 665 I independent reflections (Siemens AED diffractometer, 0 in the range 3-23", W28 scan technique and Nb-filtered radiation. The structure was solved by direct and Fourier methods and refined by fullmatrix least-squares analysis on the basis of 3278 observed reflections [ I r 2 n ( l ) ] with anisotropic thermal parameters for the Pd, CI, and P atoms (SHELX programs (51). The phenyl rings were treated as rigid groups in the last cycles of the refinement. The hydrogen atoms were placed at their geometrically calculated positions. R ~0 . 0 7 6 , R , =0.080. Further details of the crystal structure investigation can be obtained from the Fachinformationszentrum Energie, Physik, Mathematik GmbH, D-75 14 Eggenstein-Leopoldshafen 2 (FRG), by quoting the depository number CSD-52428, the names of the authors, and the journal citation.

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