The influence of orbital asymmetry on the kinetics of the gas-phase reactions of ozone with unsaturated compounds
โ Scribed by Johnson, David; Rickard, Andrew R.; McGill, Charlotte D.; Marston, George
- Book ID
- 121403272
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 148 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/A908701J
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๐ SIMILAR VOLUMES
## Abstract Rate coefficients for the reaction of ozone with a series of unsaturated oxygenated compounds are determined in air at atmospheric pressure and (298ยฑ3) K. Rate data are obtained using both relative and absolute rate techniques, and the measured rate coefficients are found to be in good
Rcccivcd 1 1 Au:just 1977 ll~ kinetics ot the grlb plea reaction bctwucn 03 (0.4-15 torr) and IIN (0.002 0.005 torr) hvc been mvcsti~:.!tcti at total pressures of 20-30 torr usmg rl 1m55 spcctromcter dctcctor. No cvldcncc ofa Ilomo~cneous-hllllolc~ul,~r reation was obtarned, and upper limits to the
The gas-phase reaction of ozone with a series of unsaturated oxygenates and with 1-pentene has been studied at ambient T (287-296 K) and atm. of air. Reaction rate p ฯญ 1 constants, in units of cm 3 molecule ฯช1 s ฯช1 , are for 2 (5H)-furanone, ฯช18 10 0.22 ฯฎ 0.05 for methacrolein, for crotonaldehyde, f