✦ LIBER ✦

The influence of chain-flexibility on the colligative properties of polyelectrolyte solutions

✍ Scribed by Theo Odijk; M. Mandel

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 274 KB
Volume: 93
Category: Article
ISSN: 0378-4371
DOI: 10.1016/0378-4371(78)90223-6

No coin nor oath required. For personal study only.

✦ Synopsis

The neglect of chain flexibility in Manning's theory of polyelectrolytes is assessed. For a flexible polyelectrolyte-the uniformly charged wormlike chain-counterion condensation is unaffected but colligative properties need to be modified. The relevant dimensionless parameter is (KLT) 1 where K i is the Debye-Hiickel radius and LT is the sum of the bare and electrostatic persistence lengths.

📜 SIMILAR VOLUMES

Influence of degree of substitution of c

Influence of degree of substitution of cyclodextrins on their colligative properties in solution

✍ Stefan Proniuk; James Blanchard 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 105 KB

The purpose of this study was to investigate the effect of the total degree of substitution (TDS) on the colligative properties of substituted cyclodextrins (CDs; i.e., b-and g-cyclodextrins substituted with sulfobutylether or hydroxypropyl groups) in solution. The osmotic pressure (OP) of aqueous C

On the equilibrium properties of polyele

On the equilibrium properties of polyelectrolyte solutions: isothermal-calorimetry

✍ V. Crescenzi 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 827 KB

The Influence of Ion Pair Formation on t

The Influence of Ion Pair Formation on the Phase Behavior of Polyelectrolyte Solutions

✍ E. Yu. Kramarenko; I. Ya. Erukhimovich; A. R. Khokhlov 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 465 KB 👁 2 views

Influence of counterion radius on the po

Influence of counterion radius on the polyelectrolyte behavior of synthetic polypeptide solutions

✍ C. Botré; M. Solinas; F. Ascoli 📂 Article 📅 1965 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 379 KB 👁 2 views

The influence of counterion radius on the polyelectrolyte behavior of poly-kcysteate in aqiieous solution under different conditions was investigated. A h e a r relationship was found between a critical concentration in solution of the synthetic charged polypeptide and the crystallographic radius of

The effect of counter-ion substitution o

The effect of counter-ion substitution on the transport properties of polyelectrolyte solutions

✍ H. Magdelénat; P. Turr; P. Tivant; M. Chemla; R. Menez; M. Drifford 📂 Article 📅 1979 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 782 KB

The effects of counter-ion substitution in aqueous polyelectrolyte solutions (chondroitin sulfate) on the two main transport phenomena of the ionic species, self-diffusion and electrical mobility, were studied experimentally by tracer methods and dynamic light scattering. The data were analyzed with

Conformation of Polyelectrolyte Chains i

Conformation of Polyelectrolyte Chains in Dilute Aqueous Solutions Investigated by Conductometry, 1. Influence of the Degree of Polymerization on the Conformation of Flexible Vinylic Polyanions and Rigid Native DNA

✍ Olga V. Davydova; Alexander N. Zelikin; Sergei I. Kargov; Vladimir A. Izumrudov 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 129 KB 👁 2 views