The neglect of chain flexibility in Manning's theory of polyelectrolytes is assessed. For a flexible polyelectrolyte-the uniformly charged wormlike chain-counterion condensation is unaffected but colligative properties need to be modified. The relevant dimensionless parameter is (KLT) 1 where K i is
On the equilibrium properties of polyelectrolyte solutions: isothermal-calorimetry
β Scribed by V. Crescenzi
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 827 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0040-6031
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π SIMILAR VOLUMES
The effects of counter-ion substitution in aqueous polyelectrolyte solutions (chondroitin sulfate) on the two main transport phenomena of the ionic species, self-diffusion and electrical mobility, were studied experimentally by tracer methods and dynamic light scattering. The data were analyzed with
## Abstract The market for commercially available isothermal titration calorimeters continues to grow as new applications and methodologies are developed. Concomitantly the number of users (and abusers) increases dramatically, resulting in a steady increase in the number of publications in which is