The Influence of Ion Pair Formation on the Phase Behavior of Polyelectrolyte Solutions
β Scribed by E. Yu. Kramarenko; I. Ya. Erukhimovich; A. R. Khokhlov
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 465 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1022-1344
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## Abstract Diβ__n__βalkyl substituted polyfluorenes with alkyl chain lengths of 6, 7, 8, 9, and 10 carbon atoms (PF6, PF7, PF8, PF9, and PF10) are studied in dilute solution in MCH using optical spectroscopy. Betaβphase is formed upon cooling in solutions (βΌ 7βΒ΅g mL^β1^) of PF7, PF8, and PF9 only,
The influence of thermal history on the formation of HECA liquid crystalline phase was studied by DSC. It was found that the degree of ordering in the liquid crystalline phase was heterogeneous, and the multiphase transformation appears when the liquid crystalline phase transformed to the isotropic