The High-Temperature Photolysis of Acetone and the Action of Free Methyl Radicals on Propane
β Scribed by Allen, Augustine O.
- Book ID
- 127046894
- Publisher
- American Chemical Society
- Year
- 1941
- Tongue
- English
- Weight
- 697 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The rotating-sector method has been applied to the photoinitiated radical-chain decomposition of formamide at 300Β°C to measure the rate constant for the bimolecular disappearance of NH2 radicals. The decomposition is propagated by the reactions Conditions were chosen so that reaction (1) was rate c
The photolysis of formamide vapor at 2062 has been studied in a flow system with results essentially similar to those obtained previously under static conditions and higher conversions. The rotating-sector technique has been applied to the radical-chain decomposition of formamide under conditions (3
The acetone-sensitized photolysis of 5-bromouracil (BrU), 1-methyl-5-bromouracil (MeBrU) and 5-bromouridine (BrUd) in deoxygenated aqueous solution in the presence of alcohols was studied on irradiation at 254 nm. BrU is converted to uracil with the release of Br-, as shown by UV analysis and high p
Abstraet Methyl methacrylate has been copolymerized with ethyl acrylate at temperatures between 35 and 65 using 2.2'-azobisisobutyronitrile as initiator. For both polymer radicals, crosspropagation is favoured energetically whereas self-propagation is favoured entropically. Values of Arrhenius param