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The Photolysis of Acetone: Diffusion of Methyl Radicals from the Light Beam and the Activation Energy of Hydrogen Abstraction

✍ Scribed by Nicholson, A. J. C.


Book ID
126282332
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
814 KB
Volume
73
Category
Article
ISSN
0002-7863

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Hydrogen abstraction reactions from orga
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Arrhenius parameters have been determined for the hydrogen-abstraction reactions: R + SiHCI, + RH + SiCl, CF, 323-46 1 5.98 & 0.06 11.77 f 0.03 8.50 CH, 333-443 4.30 f 0.08 10.83 & 0.04 8.48 C,H, 314-413 5.32 & 0.07 11.54 f 0.04 8.63 7 - l h e trend in activation energies ECH, < E c ~H , < ECF, is