The following hrrhenius parameters have been determined for the hydrogen-abstraction reactions: CF,
Reactions of methyl radicals. IV. Hydrogen abstraction from tetramethylsilane by methyl radicals produced by the photolysis of both acetone and azomethane
โ Scribed by Arican, H; Arthur, NL
- Book ID
- 121283496
- Publisher
- Commonwealth Scientific and Industrial Research Organisation Publishing
- Year
- 1983
- Tongue
- English
- Weight
- 427 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0004-9425
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Arrhenius parameters have been determined for the hydrogen-abstraction reactions: R + SiHCI, + RH + SiCl, CF, 323-46 1 5.98 & 0.06 11.77 f 0.03 8.50 CH, 333-443 4.30 f 0.08 10.83 & 0.04 8.48 C,H, 314-413 5.32 & 0.07 11.54 f 0.04 8.63 7 - l h e trend in activation energies ECH, < E c ~H , < ECF, is
A method is described for the measurement of relative rate constants for abstraction of hydrogen from ethylene at temperatures in the region of 750 K. The method is based on the effect of the addition of small quantities of propane and isobutane on the rates of formation of products in the thermal c
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