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The effect of temperature on the free radical copolymerization of methyl methacrylate with ethyl acrylate

✍ Scribed by E.L. Madruga; J. San Román; Ma.J. Rodriguez

Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
176 KB
Volume
18
Category
Article
ISSN
0014-3057

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✦ Synopsis

Abstraet Methyl methacrylate has been copolymerized with ethyl acrylate at temperatures between 35 and 65 using 2.2'-azobisisobutyronitrile as initiator. For both polymer radicals, crosspropagation is favoured energetically whereas self-propagation is favoured entropically. Values of Arrhenius parameters indicate that cross-propagation predominates for ethyl acrylate and self-propagation for methyl methacrylate.

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