𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A kinetic study of free-radical copolymerization of butyl acrylate with methyl methacrylate in solution

✍ Scribed by Enrique López Madruga; Marta Fernández-García

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
569 KB
Volume
197
Category
Article
ISSN
1022-1352

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Free‐radical copolymerization at 50°C of butyl acrylate with methyl methacrylate was carried out in benzene solution using 3 and 5 mol/L as the overall concentration of monomers. Both the reactivity ratios and the rate coefficients of copolymerization are affected by the total monomer concentration. Reactivity ratios were analyzed on the basis of the “bootstrap” model, and the copolymerization rate is interpreted assuming a penultimate effect upon the propagation reaction.

📜 SIMILAR VOLUMES

Kinetic study of high-conversion copolym
Kinetic study of high-conversion copolymerization of butyl acrylate with methyl methacrylate in solution
✍ M. Fernández-García; E. L. Madruga 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 137 KB 👁 3 views

Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme

Kinetic study of free-radical copolymeri
Kinetic study of free-radical copolymerization of methyl acrylate and methyl methacrylate in benzene
✍ Enrique López Madruga; Marta Fernández-García 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p