A kinetic study of butyl acrylate free radical polymerization in benzene solution
✍ Scribed by Marta Fernández-García; Marina Fernández-Sanz; Enrique López Madruga
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 91 KB
- Volume
- 201
- Category
- Article
- ISSN
- 1022-1352
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📜 SIMILAR VOLUMES
Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme
The copolymerization of p-tert-butoxystyrene ( TBOSt ) ( M 1 ) and di-n -butyl maleate ( DBM ) ( M 2 ) with dimethyl 2,2 -azobisisobutyrate ( MAIB ) in benzene at 60ЊC was studied kinetically and by means of ESR spectroscopy. The monomer reactivity ratios were determined to be r 1 Å 2.3 and r 2 Å 0