## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p
Kinetic study of free-radical copolymerization of ethyl α-benzoyloxymethylacrylate with methyl methacrylate in benzene
✍ Scribed by Rocío Cuervo-Rodríguez; M Carmen Fernández-Monreal; Marta Fernández-García; Enrique L. Madruga
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 430 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1022-1336
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✦ Synopsis
Abstract
From a phenomenological point of view, the Mayo‐Lewis terminal model can describe both copolymer composition and the variation of copolymerization rate for the ethyl α‐benzoyloxymethylacrylate/methyl methacrylate/benzene/2,2′‐azoisobutyronitrile system.
📜 SIMILAR VOLUMES
Butyl acrylate (BA) and methyl methacrylate (MMA) have been copolymerized in a 3 mol/L benzene solution using 2,2 -azobis(isobutyronitrile) (AIBN) as initiator over a wide composition and conversion range. The overall copolymerization parameter k p /k 1/2 t and the composition of the copolymer forme
Previously published material on the ␣-methyl styrene/methyl methacrylate (␣-MS/MMA) copolymer system at temperatures above the ceiling temperature of ␣-MS has focused on low-conversion results. Several attempts have been made to estimate copolymer reactivity ratios from experimental data, but in mo