𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The reactivities of nuclear-substituted phenyl acrylates in radical copolymerization with methyl methacrylate

✍ Scribed by A. Miller


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
240 KB
Volume
30
Category
Article
ISSN
0014-3057

No coin nor oath required. For personal study only.

✦ Synopsis


The radical copolymerizations of p-cresyl acrylate, p-chlorophenyl acrylate, p-bromophenyl acrylate and m-nitrophenyl acrylate with methyl methacrylate have been studied. The reactivity ratios for these systems have been determined for copolymerization at 60 ° in benzene; they were calculated by the linear method of Kelen and Tiid6s. Parameters Q and e for phenyl acrylates have been determined.


📜 SIMILAR VOLUMES


Radical copolymerization of acrylic mono
✍ J. San Román; E.L. Madruga 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 427 KB

The kinetics of the copolymerization of methyl methacrylate with phenyl acrylate in solution at low conversions have been examined. The ~[H]NMR spectra of copolymers show some special features which are explained by taking into account the composition and the stereochemical configuration of copolyme

Kinetic study of free-radical copolymeri
✍ Enrique López Madruga; Marta Fernández-García 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 312 KB

## Abstract The variation of copolymerization rate with composition obtained for the system methyl acrylate (1)/methyl methacrylate (2)/benzene/2,2′‐azoisobutyronitrile using standard techniques of polymerization rate measurements has been interpreted on the basis of a penultimate effect upon the p

The effect of temperature on the free ra
✍ E.L. Madruga; J. San Román; Ma.J. Rodriguez 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 176 KB

Abstraet Methyl methacrylate has been copolymerized with ethyl acrylate at temperatures between 35 and 65 using 2.2'-azobisisobutyronitrile as initiator. For both polymer radicals, crosspropagation is favoured energetically whereas self-propagation is favoured entropically. Values of Arrhenius param