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The high pressure mediated intramolecular diels-alder reaction of furans: Factors controlling cycloaddition with monoactivated dienophiles.

✍ Scribed by Laurence M. Harwood; Sarah A. Leeming; Neil S. Isaacs; Geraint Jones; John Pickard; Royston M. Thomas; David Watkin

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
313 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The Intramolecular Diels-Alder reactions of furans possessing a 2-alkyl substituent with a terminal @unsaturated ketone have been surveyed. The consequences of varying the degree of substitution of the furan, the bridging chain length, and position of the activating group on the dienophile upon the ease and stereochemistry of cycloaddition are reported.

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