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Stereochemical studies on the intramolecular diels alder reaction of furans with doubly activated dienophiles.

✍ Scribed by Laurence M. Harwood; Geraint Jones; John Pickard; Royston M. Thomas; David Watkin

Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
338 KB
Volume
29
Category
Article
ISSN
0040-4039

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✦ Synopsis

The stereochemical outcome of intramolecular Diels-Alder reactions of furans with Z-and E-2-ene-1,4-dione units attached by a bridging chain to C-2 of the furan results from modification of the steric demands of the bridging chain by the preference of the external activating group to adopt an endostereochemistry.

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