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The formation of nitrile by the reaction of NH(1Δ) with alkyne in the liquid phase

✍ Scribed by Jun Kawai; Shigeru Tsunashima; Shin Sato

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 338 KB
Volume: 110
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85482-2

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✦ Synopsis

When hydrogen azidc is photolyzed in liquid acetylene, propyne and I-buryne, acetonitrile, propionitrile and butyronitrile, respectively, are found to be formed. Acetonitrilc-& is produced when acetylem& is used as the solvent. These results suggest that the initial products formed in the reactions of NH('& with aIkynes isomerize to nitriles by the mkration of two hydrogen atoms

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