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Reactions of NH with C2H6 and C3H8 in the liquid phase

✍ Scribed by S. Tsunashima; M. Hotta; S. Sato

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
359 KB
Volume
64
Category
Article
ISSN
0009-2614

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✦ Synopsis

HNs was photolyzed in

CzHh or CsHs solution at the temperature of dry ice-methanol. The main products were N2 and CzHsNHz or nC3H-,NHz and iCsH-,NH2_ NH3 and Hz were also formed as minor products. Possible reaction mechanisms are discussed. It is suggested that alkykunine is mainly formed by the insertion of NH(a 'A) into the C-H b_onds of CzH6 or C3H8-

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