Titanocene(II)-Promoted Reaction of Thioacetals with Alkynes: Highly Stereoselective Preparation of Conjugated Dienes. -Reaction of titanium species, prepared by desulfurizative titanation of thioacetals (I), with symmetrical alkynes (II) affords the conjugated dienes (III) in good yields. When an
Formation of Conjugated Dienes by the Reaction of Titanocene Alkenylidene Complexes with Alkynes.
β Scribed by Tomohiro Shono; Yuki Hayata; Akira Tsubouchi; Takeshi Takeda
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 31 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Fluorine-nitrogen metathesis in the reaction of a cyclic iminoalane with titanocene fluorides results in unexpected cage compounds. Treatment of one of these compounds with diethyl ether leads to 1, which contains a titanium-nitrogen double bond stabilized intramolecularly by fluorine.