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Reaction of [(Cp2TiCH3)(THF)+][BPh4−] with Tripeptide Derivatives: Formation of Cationic (Peptide)titanocene Complexes

✍ Scribed by Dirk Harmsen; Gerhard Erker; Roland Fröhlich; Gerald Kehr


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
396 KB
Volume
2002
Category
Article
ISSN
1434-1948

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The dipeptide derivatives Boc-Gly-Val-OMe (2) and Boc-primary adduct 7-I (Ͼ 0 °C) resulted in methane elimination and formation of a mixture of the isomers 7-B and 7-A Ala-Val-OMe (3) selectively add the methylzirconocene cation 1 to the carbonyl oxygen atom of the N-terminal amino (isolated in a 3: