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Formation of Adamantane-Like Structures by Reaction of Titanocene Fluorides with an Iminoalane

✍ Scribed by Helge Wessel; Mavis L. Montero; Carsten Rennekamp; Herbert W. Roesky; Peihua Yu; Isabel Usón

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
110 KB
Volume
37
Category
Article
ISSN
0044-8249

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✦ Synopsis

Fluorine-nitrogen metathesis in the reaction of a cyclic iminoalane with titanocene fluorides results in unexpected cage compounds. Treatment of one of these compounds with diethyl ether leads to 1, which contains a titanium-nitrogen double bond stabilized intramolecularly by fluorine.

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