Electronically excited OH (A 'C l , v=O) products were studied in the 210 to 290 nm photolysis of the reacting system CH, t 02+CH,02. The excitation spectrum is discussed in terms of formation of 0H(A22+, u=O) and OH(X %, u=O) from CH,O, and CH(X ZII) from CH+ Simplified systems of known reactions a
The formation of CH radicals during the photolysis of CH2N2 in the presence of hydrogen and oxygen atoms
β Scribed by K.H. Becker; O. Horie; P. Wiesen
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 359 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of the reaction of CH2OH with O(3P) has been investigated in a heatable tubular reactor coupled to a photoionization mass spectrometer. The decay of CH2OH was monitored as a function of O-atom concentration ( tO determine rate constants as a function of temperature and pressure. The ra
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
The rate of the reaction CH212 + H I 2 CH,I + I , has been followed spectrophotometrically from 201 .O to 31 1 .Z0. The rate constant for the reaction I + CH,I, CH,I + I, fits the equation, log (k,/M-'sec-') = 11.45 f 0.18 -(15.11 f 0.44)/0. This value, combined with the assumption that E2 = 0 & 1 k
A study of the reaction initiated by the thermal decomposition of di-t-butyl peroxide (DTBP) in the presence of (CHa)?C=CHz (B) at 391-444 K has yielded kinetic data on a number of reactions involving CH3 (M.), (CH&CCHzCH3 (MB.) and ( C H ~) ~C C H ~C ( C H ~) Z C H ~C H ~ (MBB.) radicals. The cross