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Fragments in the UV photolysis of the CH3 and CH3O2 radicals

✍ Scribed by Ch. Kassner; P. Heinrich; F. Stuhl; S. Couris; S. Haritakis

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 442 KB
Volume: 208
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)80071-v

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✦ Synopsis

Electronically excited OH (A 'C l , v=O) products were studied in the 210 to 290 nm photolysis of the reacting system CH, t 02+CH,02. The excitation spectrum is discussed in terms of formation of 0H(A22+, u=O) and OH(X %, u=O) from CH,O, and CH(X ZII) from CH+ Simplified systems of known reactions are capable of simulating the time dependencies of the OH( A %+, v=O+X %, v=O) emission intensities and are hence consistent with the proposed photodissociation processes.

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