The Formation of a Solid from the Reaction SiCl4(g) + O2(g) → SiO2(s) + 2Cl2(g)
✍ Scribed by Michael Binnewies; Karl Jug
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 642 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
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The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected
Time-resolved emission spectroscopy of 0s ( 'Z: ) and 0s ( 'As) in CCL was used to determine the rate constants kl, , b, and k+ of the triplet state (T,) sensitized formation of the 'Z:, 'As and 'Z; states of 0s. 13 sensitizers of triplet energies 140 GE,< 309 kJ mol-' were investigated. The data ar