We calculate the vibrational encrw levels for all three possible isotopic species of the 2 'x: state of Liz and from them deduce a set of Dunham constants. Since the 2 t$ state has substantial ionic character, itsshapc isusual and so is the spacing of its vibrational levels. WC find for 'Liz, Ylo =
Vibrational structure in the photoelectron spectrum of O2+2Σg− (σg2s)
✍ Scribed by J.L. Gardner; James A.R. Samson
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 234 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
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The infrared emission observed from Hz0 or Co, when added to discharged oxygen containing Oz(r Zg> and C&(lA ) is shown to arise from their vibrational excitation in the quenching of Oz(\* $'). There was no ev&nce that O$'X> is quenched to the ground state rather than to the ' 4 state.
Relaxation rates for 02('&+) by nonradiative pathways have been determined using the fast-flow technique. 02 ('\3,+) is formed from 0 2 ( l A g ! by an energy pooling process. 02('AK) is generated by passing purified oxygen through a microwave discharge. Oxygen atoms are removed by distilling mercur
The generation of metastable O, ('Xg+) and Oz('Ag) in the H + 0, system of reactions was studied by the flow discharge chemiluminescence detection method. In addition to the Oz('Pg') and Oz(' , H0,(2A~oo) + H02(2AlohO), H02(zA~o,) + HO,(zA~oo), and H Oz(2A~oo) --+ H0,(2A&,o) emissions were detected