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The vibrational energy spectrum of the 21Σg+ state of Li2

✍ Scribed by Daniel D. Konowalow; Lyn B. Ratcliff

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 278 KB
Volume: 111
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85531-1

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✦ Synopsis

We calculate the vibrational encrw levels for all three possible isotopic species of the 2 'x: state of Liz and from them deduce a set of Dunham constants. Since the 2 t$ state has substantial ionic character, itsshapc isusual and so is the spacing of its vibrational levels. WC find for 'Liz, Ylo = 123.76 cm-l and Y~o = 1.87 cm-l, for example.

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