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The experimental heats of formation and kinetics of 1,3-biradicals using time-resolved photoacoustic calorimetry

โœ Scribed by Herman, Michael S.; Goodman, Joshua L.

Book ID
121461081
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
463 KB
Volume
110
Category
Article
ISSN
0002-7863

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The energetics and lifetimes of a number of substituted oletin and diene triplets have been measured using photoacoustic calorimetry. All the acyclic triplets studied have triplet energies less than their spectroscopic values. This suggests they prefer a twisted relaxed geometry.