𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The heat of formation of the benzophenone ketyl radical by time-resolved photoacoustic calorimetry

✍ Scribed by Luis G. Arnaut; Richard A. Caldwell


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
431 KB
Volume
65
Category
Article
ISSN
1010-6030

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Enthalpy of formation of the benzoyl rad
✍ J.A.Martinho SimΓ΅es; D. Griller πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 234 KB

The energetics of the benzoyl radical have been studied by photoacoustic calorimetry. The value obtained for D[PhC (0)-H]. 371? 11 kJ mol-' (89 + 3 kcal mol-' ), agrees with an early result derived from iodination kinetic experiments and does not support a recent suggestion that the radical is reson

The energetics and kinetics of relaxed a
✍ Joseph A. Lavilla; Joshua L. Goodman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 388 KB

The energetics and lifetimes of a number of substituted oletin and diene triplets have been measured using photoacoustic calorimetry. All the acyclic triplets studied have triplet energies less than their spectroscopic values. This suggests they prefer a twisted relaxed geometry.

Reduction of triphenyl methane dyes by t
✍ A.C. Bhasikuttan; L.V. Shastri; A.V. Sapre; K.V.S. Rama Rao; J.P. Mittal πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 742 KB

The reduction of four triphenyl methane (TPM) dyes (brilliant green (BG+), malachite green (MG' ), crystal violet (CV+) and methyl green (MEG")) by diphenyl ketyl radicals (BPH' ) and hydrated electrons (e,,-) was studied by pulse radiolytic kinetic spectrophotometry. The rate constants for the re