✦ LIBER ✦

The energetics and kinetics of relaxed alkene triplet states as determined by pulsed time-resolved photoacoustic calorimetry

✍ Scribed by Joseph A. Lavilla; Joshua L. Goodman

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 388 KB
Volume: 141
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80109-4

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✦ Synopsis

The energetics and lifetimes of a number of substituted oletin and diene triplets have been measured using photoacoustic calorimetry. All the acyclic triplets studied have triplet energies less than their spectroscopic values. This suggests they prefer a twisted relaxed geometry.