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Use of pulsed time-resolved photoacoustic calorimetry to determine the strain energy of trans-1-phenylcyclohexene and the energy of the relaxed 1-phenylcyclohexene triplet

✍ Scribed by Goodman, Joshua L.; Peters, Kevin S.; Misawa, H.; Caldwell, R. A.


Book ID
126951862
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
394 KB
Volume
108
Category
Article
ISSN
0002-7863

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The energetics and kinetics of relaxed a
✍ Joseph A. Lavilla; Joshua L. Goodman πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 388 KB

The energetics and lifetimes of a number of substituted oletin and diene triplets have been measured using photoacoustic calorimetry. All the acyclic triplets studied have triplet energies less than their spectroscopic values. This suggests they prefer a twisted relaxed geometry.