The energetics and kinetics of relaxed a
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Joseph A. Lavilla; Joshua L. Goodman
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Article
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1987
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Elsevier Science
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English
β 388 KB
The energetics and lifetimes of a number of substituted oletin and diene triplets have been measured using photoacoustic calorimetry. All the acyclic triplets studied have triplet energies less than their spectroscopic values. This suggests they prefer a twisted relaxed geometry.