β Scribed by K.A McLauchlan; D.G Stevens
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The antiphase structure (APS) of CIDEP spectra of spin correlated radical pairs in viscous liquids is investigated theoretically in a free diffusion model for relative motion of radicals. A very simple and accurate formula for relative APS amplitude is derived. This formula predicts a very small AP
The transfer of hyperfine-dependent electron spin polarization from a primary to a secondary radical is shown for the first time, and its implications to the interpretation ofCIDEP spectra discussed. A new method for comparing the relative signs of hypefine coupling constants in different radicals i
Transient alkyl radicals and triplet-state molecules are generated simultaneously in solution by laser flash irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The presence of triplet-state molecules is found to induce emis