β Scribed by C.D Buckley; K.A McLauchlan
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Transient alkyl radicals and triplet-state molecules are generated simultaneously in solution by laser flash irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The presence of triplet-state molecules is found to induce emis
In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here t
Chemically induced dynamic electron polarization (CIDEP) generated through the interaction of the excited triplet state of benzophenone with the 2,2,6,6,-tetramethyl-l-piperidinyloxyl (TEMPO) radical was investigated by time-resolved ESR spectroscopy in benzene solution. We carefully examined what f
Magnetic field effects are reported from radical combination reactions involving electronically excited diphenylmethyl and para-substituted benzyl radicals created, along with a ground-state radical, by laser flash photolysis of micellized ketones. A parallel CIDEP study of ground-state radicals dis