✦ LIBER ✦

Spin-selective recombination in geminate radical pairs involving electronically excited radicals studied by MFE and CIDEP

✍ Scribed by S.N. Batchelor; K.A. McLauchlan; I.A. Shkrob

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 590 KB
Volume: 214
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)85674-d

No coin nor oath required. For personal study only.

✦ Synopsis

Magnetic field effects are reported from radical combination reactions involving electronically excited diphenylmethyl and para-substituted benzyl radicals created, along with a ground-state radical, by laser flash photolysis of micellized ketones. A parallel CIDEP study of ground-state radicals displayed inverse behaviour. The results are thought to shed light on the diffusional processes occurring inmicellar solutions.

📜 SIMILAR VOLUMES

Generation and recombination of free rad

Generation and recombination of free radicals in organic materials studied by electron spin resonance

✍ G Fritsch; C.T López; J.L Rodríguez 📂 Article 📅 1974 🏛 Elsevier Science ⚖ 457 KB

Free Radical Formation from Excited Stat

Free Radical Formation from Excited States of Aliphatic Carboxylic Acids and esters in solution as studied by electron spin resonance

✍ Tony Kaiser; Loris Grossi; Hanns Fischer 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 547 KB

## Abstract During UV.‐irradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.‐spectroscopy. The structures of the radicals point to α‐cleavage, β‐dehalogenati