Chemically induced dynamic electron polarization (CIDEP) in nitrogen heterocyclic radicals: a stringent test of polarization theory
β Scribed by S. Basu; K.A. McLaughlan; G.R. Sealy
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 495 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Tks resOlWd electron paramzgetic resonance spectioscopy was used to examine the electrdn spin'.pokuization .' in several radicals produced in &ise'iadiolysis of aqdkus alcoholic solutions, The observation of the dislribution of ,. polarized intensities in the vario& ltg'&ine lines in &I EPR miuing o
Transient alkyl radicals and triplet-state molecules are generated simultaneously in solution by laser flash irradiation, and chemically induced electron polarization (CIDEP) of the radicals is studied by time-resolved ESR spectroscopy. The presence of triplet-state molecules is found to induce emis
In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here t