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Chemically induced dynamic electron polarization. The isotropic hyperfine coupling and the CIDEP of radicals produced by pulse radiolysis

โœ Scribed by A.D. Trifunac; E.C. Avery


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
395 KB
Volume
28
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Tks resOlWd electron paramzgetic resonance spectioscopy was used to examine the electrdn spin'.pokuization .' in several radicals produced in &ise'iadiolysis of aqdkus alcoholic solutions, The observation of the dislribution of ,. polarized intensities in the vario& ltg'&ine lines in &I EPR miuing of the electron-nuclez sistes ~'radicalpnirs. spectrum plovides yet another indication o&e S-To ': in OIJF recept publication tie have described the experime$d verification of the radical pair hdel.bf '.


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In flash-photolysis experiments the phase of RPM polarization in the radicals commonly changes in time after the flash, the patterns observed at longer times being apparently inconsistent with observations on the same radical systems made using alternative experimental techniques. It is shown here t