โ Scribed by A.I. Shushin
No coin nor oath required. For personal study only.
The antiphase structure (APS) of CIDEP spectra of spin correlated radical pairs in viscous liquids is investigated theoretically in a free diffusion model for relative motion of radicals. A very simple and accurate formula for relative APS amplitude is derived.
This formula predicts a very small APS amplitude for the radical pair 2(CH&CH at T= -45ยฐC. The amplitude is two orders of magnitude smaller than the experimental one, suggesting that the free-diffusion-model description of the relative motion of radicals is not correct.
๐ SIMILAR VOLUMES
Shortly after their formation, transient free radicals trapped in micelles exhibit electron spin resonance (ESR) spectra with "antiphase" lineshapes, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is demonstrated that this hitherto unexplained effect is co
Hore and McLauchlan that shortly after their formation geminate isopropylketyl radicals in isopropanol at law temperature ( ~200 K) exhibit ESR spectra with "antiphase" lineshape, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is shown that a theory which
The ESR lineshape of spin-correlated radical pairs (RP) diffusing in a small volume is calculated within the sudden perturbation approach for space dimensionalities D = 1, 2, 3. It is shown that in 2D and 3D models the RP spin dynamics are described by a Bioch-type equation quite accurately. A simpl