Flip-angle effects in Fourier-transform EPR spectra of spin-correlated radical pairs
β Scribed by C.R. Timmel; P.J. Hore
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 445 KB
- Volume
- 226
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Hore and McLauchlan that shortly after their formation geminate isopropylketyl radicals in isopropanol at law temperature ( ~200 K) exhibit ESR spectra with "antiphase" lineshape, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is shown that a theory which
The spin-correlated radical pairs (SCRPs) formed by photoinduced electron transfer from zinc tetrakis(4-sulfonatophenyl)porphyrin (ZnTPPS) to quinones in micelles of the cationic surfactant cetyltrimethylammonium chloride (CTAC) were studied by means of Fourier transform EPR (FT-EPR). It is shown th
We demonstrate the potential of high-field (HF) time-resolved electron paramagnetic resonance (EPR) spectroscopy to reveal unique information about electron transfer processes and the structure of photosynthetic systems. The lineshapes and electron spin polarization (ESP) of spin-correlated radical