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Electron spin resonance of spin-correlated radical pairs

✍ Scribed by C.D. Buckley; D.A. Hunter; P.J. Hore; K.A. McLauchlan

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 484 KB
Volume: 135
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)85162-x

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✦ Synopsis

Shortly after their formation, transient free radicals trapped in micelles exhibit electron spin resonance (ESR) spectra with "antiphase" lineshapes, i.e. lines with their low-field halves in emission and high-field halves in absorption. It is demonstrated that this hitherto unexplained effect is consistent with the detection of ESR transitions in geminate radical pairs before the radicals have had time to diffuse apart.

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