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The effect of water on the conductance mechanism and the solvation of the proton' in 2-methoxyethanol water mixtures at 25°C

✍ Scribed by G.V. Merken; H.P. Thun; F. Verbeek

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 312 KB
Volume: 21
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(76)85101-8

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✦ Synopsis

Conductivity measurements at 25% on solutions of hydrogen chloride in various mixtures of 2-methoxyethanol and water, are reported. The experimental data were analysed by means of the Fuoss-Onsager equation. The limiting equivalent conductivity and the association constant were determined. This study focusses on the effect of the decreasing amount of water in the solvent mixture, on the ion-solvent interactions and discusses aspects of the salvation and the structure of the electrolytic solutions.

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