✦ LIBER ✦

The effect of supplemental t-butyl radicals on the pyrolysis of tertiarybutylarsine, tertiarybutylphosphine, and ditertiarybutylarsine

✍ Scribed by S.H. Li; N.I. Buchan; C.A. Larsen; G.B. Stringfellow

Publisher: Elsevier Science
Year: 1989
Tongue: English
Weight: 644 KB
Volume: 98
Category: Article
ISSN: 0022-0248
DOI: 10.1016/0022-0248(89)90146-2

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Solvent effects on the nitrogen hyperfin

Solvent effects on the nitrogen hyperfine splitting constant of the t-butyl-t-butoxy nitroxyl radical

✍ Edward G. Janzen; Gregory A. Coulter 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 179 KB

On the configurational stability of an o

On the configurational stability of an oxiranyl radical. A comparison of the radical trapping efficiencies of triphenyltin hydride and t-butyl hypochlorite.

✍ L.J. Altman; Robert C. Baldwin 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 167 KB

The photolysis of 3,3-dimethylbutan-2-on

The photolysis of 3,3-dimethylbutan-2-one (methyl t-butyl ketone) and the decomposition of the acetyl radical

✍ H. M. Frey; I. C. Vinall 📂 Article 📅 1973 🏛 John Wiley and Sons 🌐 English ⚖ 776 KB

## Abstract The photolysis of 3,3‐dimethylbutan‐2‐one (MTBK) has been studied in the gas phase at 408 and 326 K, mainly with light of 313 nm wavelength. At the higher temperature, the major products were methane, ethane, isobutane, isobutene, neopentane, tetramethylbutane, and carbon monoxide. At 3

On the structure of acyl nitroxides (nit

On the structure of acyl nitroxides (nitroxones). Spin trapping aminoacyl radicals with t-nitrosobutane (t-NB) and phenyl t-butyl nitrone (PBN)

✍ Edward G. Janzen; Edward R. Davis; Dale E. Nutter Jr. 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 240 KB

a-Ketonitroxides (nitroxones) are relatively persistent nitroxides produced either from oxidation of hydroxamic acids (1) or by spin trapping (2). Since nitroxones are isoelectronic with semidiones (3) it is reasonable to assume that the carbonyl and nitroxyl functions are part of a planar 5n-electr

Temperature and time effect on the conce

Temperature and time effect on the concentrations of free radicals in coal: Evidence from laboratory pyrolysis experiments

✍ Nansheng Qiu; Huili Li; Zhijun Jin; Yinkang Zhu 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 221 KB

The relationships between free radical concentration (N g ) and vitrinite reflectance (%R o ) of coal were tested through 36 laboratory anhydrous pyrolysis experiments. The experiments were carried out at isothermal reactor with pyrolysis temperatures ranging from 300 to 550 °C over 30-480 min. The

The formation of (CH3)3Ċ, H2ĊC(Me)2OH an

The formation of (CH3)3Ċ, H2ĊC(Me)2OH and ĊH3 radicals in the radiolysis of aqueous t-butyl alcohol: on the solvation of t-butyl alcohol by water

✍ K.V.S. Rao; M.C.R. Symons 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 170 KB

Esppsure of aqueous glassy solutions of f-butyl alcohol to 6oCo vlays at 77°K gave ESR spectra characteristic of h!e& and H2CC(hfe)20H radicals. The results for the former were unusual in fh?t, for very dilute aqueous solutions and for solutions of 0.4 mole fraction through to the pure alcohol, all