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The formation of (CH3)3Ċ, H2ĊC(Me)2OH and ĊH3 radicals in the radiolysis of aqueous t-butyl alcohol: on the solvation of t-butyl alcohol by water

✍ Scribed by K.V.S. Rao; M.C.R. Symons

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
170 KB
Volume
20
Category
Article
ISSN
0009-2614

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✦ Synopsis

Esppsure of aqueous glassy solutions of f-butyl alcohol to 6oCo vlays at 77°K gave ESR spectra characteristic of h!e& and H2CC(hfe)20H radicals. The results for the former were unusual in fh?t, for very dilute aqueous solutions and for solutions of 0.4 mole fraction through to the pure alcohol, all the Me& radicals were apparenGy freely rotating, whilst for solutions in the mole fraction region 0.05 to 0.4, some or all of these radicals were stationary. Implications with respect to water structura1 factors zre discussed.

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