The effect of reagent vibrational energy on measured reaction rate constants
β Scribed by John H. Birely; John L. Lyman
- Publisher
- Elsevier Science
- Year
- 1975
- Weight
- 867 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0047-2670
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Many cellular reactions involve a reactant in solution binding to or dissociating from a reactant attached to a surface. Most studies assume that the reactions occur on this surface, when in actuality the receptors usually lie in a thin layer on top of it. The effect of this layer is considered, par
An upper bbund of 6 X 10" cm3/mole s on the rate constant for the reaction. of atomic oxygen with vibrntional-I$ excited Yz has been deduced from laboiatory'observations and from detailed computer &ulations. From this result it can be shown that no more than 30% of the vibrational energy of Hz is e
## Abstract Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Ξ__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for