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Steric Effects on Reaction Rates. Rate and equilibrium constants for oxidation of cyclanols

✍ Scribed by Paul Müller; Jacky Blanc

Publisher
John Wiley and Sons
Year
1980
Tongue
German
Weight
393 KB
Volume
63
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Equilibrium constants for oxidations of cyclanols by cyclohexanone in benzene have been determined in the presence of aluminium isopropoxide. The free energies of the equilibrium (Δ__G__~ox~) are correlated with equilibrium constants for dissociation of cyanohydrins, rate constants for cyclanol oxidation with chromic acid, ketone reduction with sodium borohydride and trifluoroethanolysis of tosylates.

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